化学实验操作技能测试评分者效应研究*

基于Rasch模型对化学实验操作技能测试的评分者效应开展研究。通过对Infit、Outfit、t、怀特图和宽严度波动图等的分析,研究测试中评委的宽严度、内部一致性、外部一致性以及评委与考生间的偏差规律。得到系列减弱化学实验操作技能测试中评分者效应的建议。     

Enhanced Operational Durability of Thermally Activated Delayed Fluorescence-Based Organic Light-Emitting Diodes with a Triazine Electron Transporter

In organic light-emitting diodes (OLEDs) based on materials that show thermally activated delayed fluorescence (TADF), the internal quantum efficiency of 100 % can be obtained without using phosphorescence-based organometallics that contain rare metals. Therefore, with TADF-based emitters, it is possible to fabricate high-performing OLEDs at a lower cost. However, compared with fluorescence- and phosphorescence-based OLEDs, an understanding of degradation mechanisms in TADF-based OLEDs is still insufficient for future commercialization. In particular, it is widely recognized that the development of electron transport materials is crucial for improving OLED characteristics, especially driving voltages and operational durability. In this study, it was demonstrated that the operational durability of TADF-based OLEDs was greatly improved by introducing a triazine-based material of 2,4,6-tris(1,1′-biphenyl-4-yl)-[1,3,5]triazine (pT2T) as a hole-blocking layer (HBL) compared with a conventional HBL material of 2,4,6-tris(biphenyl-3-yl)-[1,3,5]triazine (T2T). Several experiments were carried out to make the reasons of the improved durability clearer, and attributed the improved durability to the shift of a carrier recombination zone from the emitting layer/HBL interface and the suppressed formation of excited-state quenchers in the pT2T HBL, because of the higher electron mobility of pT2T and the better stability of its radical anion state.     

电感耦合等离子体原子发射光谱(ICP-AES)法测定胡蜂酒中无机元素

采用电感耦合等离子体原子发射光谱法测定胡蜂酒中20种无机元素,建立无机元素对照指纹图谱,对重金属元素进行风险评估。结果表明,胡蜂酒中无机元素种类丰富,其中P、K、Na元素占测定总元素的96.14%。有害元素Pb、Cd、As、Hg、Cu含量符合国家药典标准要求,Cu的靶标危险系数(THQ)为1.00×10^-2,THQ<1说明摄入的重金属对人体健康造成的影响不明显。不同产区胡蜂酒金属元素含量存在差异,根据金属元素图谱得出元素含量按原子序数顺序出现相似的分布态势。结果表明,胡蜂酒中含有丰富的金属元素,很多为营养微量元素,有害元素(Pb、Cd、As、Hg、Cu)含量符合药典要求,从金属元素方面单一来看,饮用胡蜂酒没有明显的健康风险。胡蜂酒无机元素指纹图谱可为胡蜂酒的鉴别提供一定的的参考依据。     

A new scheme for solving nonlinear Stratonovich Volterra integral equations via Bernoulli’s approximation

In this paper, an efficient method for solving nonlinear Stratonovich Volterra integral equations is proposed. By using Bernoulli polynomials and their stochastic operational matrix of integration, these equations can be reduced to the system of nonlinear algebraic equations with unknown Bernoulli coefficient which can be solved by numerical methods such as Newton’s method. Also, an error analysis is valid under fairly restrictive conditions. Furthermore, in order to show the accuracy and reliability of the proposed method, the new approach is compared with the block pulse functions method by some examples. The obtained results reveal that the proposed method is more accurate and efficient than the block pulse functions method.     

The fundamental theorem of mutual insurance

The essence of mutual insurance is the notion that re-distributing risk in a pool of risks is more beneficial than taking the risk alone. Interpreting ‘more beneficial’ as an increase in utility and considering sequences of exchangeable risks, we are able to formalize this notion from the policyholder’s perspective and demonstrate its validity for various alternative preference functionals (e.g., expected utility, Choquet expected utility, and distortion risk measures). To obtain this result, we exploit that for a sequence of exchangeable risks the corresponding sequence of arithmetical averages is a reversed martingale.We conclude that pooling risks is fundamental for understanding the mechanisms of insurance because it favourably affects the utility of policyholders, and we refer to this phenomenon as the ‘utility-improving effect of risk pooling’. Moreover, we demonstrate that the utility of the policyholder is (strictly) increasing with the size of the risk pool.     

A new operational vector approach for time-fractional subdiffusion equations of distributed order based on hybrid functions

This research study deals with the numerical solutions of linear and nonlinear time-fractional subdiffusion equations of distributed order. The main aim of our approach is based on the hybrid of block-pulse functions and shifted Legendre polynomials. We produce a novel and exact operational vector for the fractional Riemann–Liouville integral and use it via the Gauss–Legendre quadrature formula and collocation method. Consequently, we reduce the proposed equations to systems of equations. The convergence and error bounds for the new method are investigated. Six problems are tested to confirm the accuracy of the proposed approach. Comparisons between the obtained numerical results and other existing methods are provided. Numerical experiments illustrate the reliability, applicability, and efficiency of the proposed method.     

任意阶高运算恒定性分抗逼近电路--标度格型级联双口网络

标度拓展经典负半阶分抗逼近电路,可实现具有任意分数阶微积算子运算功能的分抗逼近电路,但牺牲了运算恒定性.从电路网络的角度分析具有恒定运算性能的负半阶Carlson分形格分抗逼近电路.根据标度分形格分抗逼近电路的等效无源双口网络,探讨该双口网络右侧端口的运算有效性,设计具有高运算恒定性的任意阶标度分形格分抗逼近电路.结合负实零极点对基元系统的零极点分布及其局域化特性,阐述具有任意实数阶微积算子运算功能的标度分形格分抗逼近电路运算振荡现象的物理本质,并从理论上分析有效抑制频域运算振荡现象的方法.结合对称阻容T型节电路优化理论及方法,对任意阶对称格型级联双口网络的频域逼近性能进行优化,获得具有高逼近效益的任意阶标度分形格分抗逼近电路.具有低振荡幅度的任意阶对称格型级联双口网络为高运算恒定性的分抗逼近电路设计及应用提供了一种新方法及思路.     

Tail asymptotics of random sum and maximum of log-normal risks

In this paper we derive the asymptotic behaviour of the survival function of both random sum and random maximum of log-normal risks. As for the case of finite sum and maximum investigated in Asmussen and Rojas-Nandayapa (2008) also for the more general setup of random sums and random maximum the principle of a single big jump holds. We investigate both the log-normal sequences and some related dependence structures motivated by stationary Gaussian sequences.     

Likelihood Inference under Generalized Hybrid Censoring Scheme with Comp eting Risks

Statistical inference is developed for the analysis of generalized type-II hybrid censoring data under exponential competing risks model. In order to solve the problem that approximate methods make unsatisfactory performances in the case of small sample size, we establish the exact conditional distributions of estimators for parameters by conditional moment generating function(CMGF). Furthermore, confidence intervals(CIs) are constructed by exact distributions, approximate distributions as well as bootstrap method respectively, and their performances are evaluated by Monte Carlo simulations. And finally, a real data set is analyzed to illustrate all the methods developed here.     

Versatile wideband balanced detector for quantum optical homodyne tomography

We present a comprehensive theory and an easy to follow method for the design and construction of a wideband homodyne detector for time-domain quantum measurements. We show how one can evaluate the performance of a detector in a specific time-domain experiment based on the electronic spectral characteristic of that detector. We then present and characterize a high-performance detector constructed using inexpensive, commercially available components such as low-noise high-speed operational amplifiers and high-bandwidth photodiodes. Our detector shows linear behavior up to a level of over 13 dB clearance between shot noise and electronic noise, in the range from DC to 100 MHz. The detector can be used for measuring quantum optical field quadratures both in the continuous-wave and pulsed regimes with standard commercial mode-locked lasers.